Pathways to commercially viable organic photovoltaic materials – Nature

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.
Advertisement
Nature Materials (2026)
Organic photovoltaics (OPVs) are a pathway to sustainable energy solutions in various applications, but the challenge of developing materials that simultaneously fulfil stringent cost, efficiency and stability requirements has limited widespread adoption. Here we examine the critical factors shaping the transition of OPV materials from laboratory research to real-world deployment, focusing on materials design, scalable manufacturing and device reliability. Recent laboratory-scale proof-of-concept and prototype demonstrations have advanced the development of OPV materials with device efficiencies that exceed 21%, yet overcoming scale-up challenges remains essential for commercial viability. To facilitate this lab-to-fab transition, we discuss four key aspects that are expected to define the next decade of sustainable OPV: cost-effectiveness, green solvents for processing, stability and efficiency. By integrating these considerations, we highlight the advantages of OPV materials, including high power-to-weight ratios, intrinsic mechanical flexibility and tailored spectral selectivity for greenhouse agrivoltaics, to accelerate their commercialization.
This is a preview of subscription content, access via your institution
Access Nature and 54 other Nature Portfolio journals
Get Nature+, our best-value online-access subscription
$32.99 / 30 days
cancel any time
Subscribe to this journal
Receive 12 print issues and online access
$259.00 per year
only $21.58 per issue
Buy this article
USD 39.95
Prices may be subject to local taxes which are calculated during checkout
Furlan, F. & Gasparini, N. Organic photovoltaics surpass the 20% efficiency milestone. Nat. Mater. 24, 336–337 (2025).
Article  CAS  PubMed  Google Scholar 
Chen, H. et al. Organic solar cells with 20.82% efficiency and high tolerance of active layer thickness through crystallization sequence manipulation. Nat. Mater. 24, 444–453 (2025).
Article  CAS  PubMed  Google Scholar 
Li, C. et al. Non-fullerene acceptors with high crystallinity and photoluminescence quantum yield enable >20% efficiency organic solar cells. Nat. Mater. 24, 433–443 (2025).
Article  CAS  PubMed  Google Scholar 
Wang, L. et al. Diluted ternary heterojunctions to suppress charge recombination for organic solar cells with 21% efficiency. Adv. Mater. 37, 2419923 (2025).
Article  CAS  Google Scholar 
Li, C. et al. Organic solar cells with 21% efficiency enabled by a hybrid interfacial layer with dual-component synergy. Nat. Mater. 24, 1626–1634 (2025).
Article  CAS  PubMed  Google Scholar 
Zhu, L. et al. Achieving 20.8% organic solar cells via additive-assisted layer-by-layer fabrication with bulk p-i-n structure and improved optical management. Joule 8, 3153–3168 (2024).
Article  CAS  Google Scholar 
Park, S. et al. Self-powered ultra-flexible electronics via nano-grating-patterned organic photovoltaics. Nature 561, 516–521 (2018).
Article  CAS  PubMed  Google Scholar 
Corzo, D. et al. High-performing organic electronics using terpene green solvents from renewable feedstocks. Nat. Energy 8, 62–73 (2022).
Article  Google Scholar 
Li, Y., Huang, X., Sheriff, H. K. M. & Forrest, S. R. Semitransparent organic photovoltaics for building-integrated photovoltaic applications. Nat. Rev. Mater. 8, 186–201 (2022).
Article  Google Scholar 
Yi, J., Zhang, G., Yu, H. & Yan, H. Advantages, challenges and molecular design of different material types used in organic solar cells. Nat. Rev. Mater. 9, 46–62 (2023).
Article  Google Scholar 
Zhao, Y. P. et al. Achieving sustainability of greenhouses by integrating stable semi-transparent organic photovoltaics. Nat. Sustain. 6, 539–548 (2023).
Article  Google Scholar 
Wang, Z. et al. Self-sustaining personal all-day thermoregulatory clothing using only sunlight. Science 382, 1291–1296 (2023).
Article  CAS  PubMed  Google Scholar 
Yang, N. et al. Molecular design for low-cost organic photovoltaic materials. Nat. Rev. Mater. 10, 404–424 (2025).
Article  Google Scholar 
Burgués-Ceballos, I. et al. Transparent organic photovoltaics: a strategic niche to advance commercialization. Joule 5, 2261–2272 (2021).
Article  Google Scholar 
Ravishankar, E. et al. Organic solar powered greenhouse performance optimization and global economic opportunity. Energy Environ. Sci. 15, 1659–1671 (2022).
Article  Google Scholar 
Feroze, S. et al. Long term outdoor performance evaluation of printed semitransparent organic photovoltaic modules for BIPV/BAPV applications. Energy Environ. Sci. 18, 674–688 (2025).
Article  CAS  Google Scholar 
Wang, D. et al. High-performance and eco-friendly semitransparent organic solar cells for greenhouse applications. Joule 5, 945–957 (2021).
Article  CAS  Google Scholar 
Wu, Q. et al. High-performance organic photovoltaic modules using eco-friendly solvents for various indoor application scenarios. Joule 6, 2138–2151 (2022).
Article  CAS  Google Scholar 
Wang, Z. et al. Mechanically robust and stretchable organic solar cells plasticized by small-molecule acceptors. Science 387, 381–387 (2025).
Article  CAS  PubMed  Google Scholar 
Reb, L. K. et al. Perovskite and organic solar cells on a rocket flight. Joule 4, 1880–1892 (2020).
Article  CAS  Google Scholar 
Li, Y. et al. Radiation hardness of organic photovoltaics. Joule 9, 101800 (2025).
Article  CAS  Google Scholar 
Ho-Baillie, A. W. Y. et al. Emerging photovoltaics for onboard space applications. Nat. Rev. Mater. 9, 759–761 (2024).
Article  CAS  Google Scholar 
Xu, Z. et al. In situ performance and stability tests of large-area flexible polymer solar cells in the 35-km stratospheric environment. Natl Sci. Rev. 10, nwac285 (2023).
Article  CAS  PubMed  Google Scholar 
Datt, R., Lee, H. K. H., Zhang, G. C., Yip, H. L. & Tsoi, W. C. Organic solar cells at stratospheric condition for high altitude platform station application. Chin. J. Chem. 40, 2927–2932 (2022).
Article  CAS  Google Scholar 
Wang, Y. et al. Highly efficient and stable organic photovoltaic cells for underwater applications. Adv. Mater. 36, 2402575 (2024).
Article  CAS  Google Scholar 
Röhr, J. A., Sartor, B. E., Lipton, J. & Taylor, A. D. A dive into underwater solar cells. Nat. Photon. 17, 747–754 (2023).
Article  Google Scholar 
McCulloch, I., Chabinyc, M., Brabec, C., Nielsen, C. B. & Watkins, S. E. Sustainability considerations for organic electronic products. Nat. Mater. 22, 1304–1310 (2023).
Article  CAS  PubMed  Google Scholar 
Guo, J. & Min, J. A cost analysis of fully solution-processed ITO-free organic solar modules. Adv. Energy Mater. 9, 1802521 (2018).
Article  Google Scholar 
Machui, F. et al. Cost analysis of roll-to-roll fabricated ITO free single and tandem organic solar modules based on data from manufacture. Energy Environ. Sci. 7, 2792–2802 (2014).
Article  CAS  Google Scholar 
Emmott, C. J. M., Urbina, A. & Nelson, J. Environmental and economic assessment of ITO-free electrodes for organic solar cells. Sol. Energy Mater. Sol. Cells 97, 14–21 (2012).
Article  CAS  Google Scholar 
Sun, R. et al. High-speed sequential deposition of photoactive layers for organic solar cell manufacturing. Nat. Energy 7, 1087–1099 (2022).
Article  CAS  Google Scholar 
Gambhir, A., Sandwell, P. & Nelson, J. The future costs of OPV—a bottom-up model of material and manufacturing costs with uncertainty analysis. Sol. Energy Mater. Sol. Cells 156, 49–58 (2016).
Article  CAS  Google Scholar 
Sun, R. et al. Cost-efficient recycling of organic photovoltaic devices. Joule 8, 2523–2538 (2024).
Article  CAS  Google Scholar 
Burke, D. J. & Lipomi, D. J. Green chemistry for organic solar cells. Energy Environ. Sci. 6, 2053–2066 (2013).
Article  CAS  Google Scholar 
Xiong, H. et al. General room-temperature Suzuki–Miyaura polymerization for organic electronics. Nat. Mater. 23, 695–702 (2024).
Article  CAS  PubMed  Google Scholar 
Zhang, X. et al. Direct arylation polycondensation-derived polythiophene achieves over 16% efficiency in binary organic solar cells via tuning aggregation and miscibility. Adv. Energy Mater. 14, 2402239 (2024).
Article  CAS  Google Scholar 
Po, R., Bianchi, G., Carbonera, C. & Pellegrino, A. ‘All that glisters is not gold’: an analysis of the synthetic complexity of efficient polymer donors for polymer solar cells. Macromolecules 48, 453–461 (2015).
Article  CAS  Google Scholar 
Sun, C. et al. A low cost and high performance polymer donor material for polymer solar cells. Nat. Commun. 9, 743 (2018).
Article  PubMed  PubMed Central  Google Scholar 
Ren, J. et al. Molecular design revitalizes the low-cost PTV-polymer for highly efficient organic solar cells. Natl Sci. Rev. 8, nwab031 (2021).
Article  CAS  PubMed  PubMed Central  Google Scholar 
Yan, C. et al. Non-fullerene acceptors for organic solar cells. Nat. Rev. Mater. 3, 18003 (2018).
Article  CAS  Google Scholar 
Yuan, J. et al. Single-junction organic solar cell with over 15% efficiency using fused-ring acceptor with electron-deficient core. Joule 3, 1140–1151 (2019).
Article  CAS  Google Scholar 
Li, C. et al. Non-fullerene acceptors with branched side chains and improved molecular packing to exceed 18% efficiency in organic solar cells. Nat. Energy 6, 605–613 (2021).
Article  CAS  Google Scholar 
Zeng, R. et al. Achieving 19% efficiency in non-fused ring electron acceptor solar cells via solubility control of donor and acceptor crystallization. Nat. Energy 9, 1117–1128 (2024).
CAS  Google Scholar 
Shao, Y. M. et al. Low-cost organic photovoltaic materials with great application potentials enabled by developing isomerized non-fused ring acceptors. Sci. China Chem. 66, 1101–1110 (2023).
Article  CAS  Google Scholar 
Riera-Galindo, S. et al. High polymer molecular weight yields solar cells with simultaneously improved performance and thermal stability. Small 20, 2311735 (2024).
Article  CAS  Google Scholar 
Shi, M. M. et al. The intrinsic role of molecular mass and polydispersity index in high-performance non-fullerene polymer solar cells. Adv. Energy Mater. 11, 2002709 (2021).
Article  CAS  Google Scholar 
Xu, L. Y. et al. Real-time monitoring polymerization degree of organic photovoltaic materials toward no batch-to-batch variations in device performance. Nat. Commun. 15, 1248 (2024).
Article  CAS  PubMed  PubMed Central  Google Scholar 
Yu, Y. et al. Cost-effective cathode interlayer material for scalable organic photovoltaic cells. J. Am. Chem. Soc. 146, 8697–8705 (2024).
Article  CAS  PubMed  Google Scholar 
Karki, A., Gillett, A. J., Friend, R. H. & Nguyen, T. Q. The path to 20% power conversion efficiencies in nonfullerene acceptor organic solar cells. Adv. Energy Mater. 11, 2003441 (2020).
Article  Google Scholar 
Lee, S. et al. Eco-friendly polymer solar cells: advances in green-solvent processing and material design. ACS Nano 14, 14493–14527 (2020).
Article  CAS  PubMed  Google Scholar 
Du, Z. et al. Additive-free molecular acceptor organic solar cells processed from a biorenewable solvent approaching 15% efficiency. Mater. Horiz. 10, 5564–5576 (2023).
Article  CAS  PubMed  Google Scholar 
Jeon, H. et al. High-performance, ambient-processable organic solar cells achieved by single terpene-based entirely eco-friendly process. J. Mater. Chem. A 13, 230–242 (2024).
Article  Google Scholar 
Zhang, R. et al. Equally high efficiencies of organic solar cells processed from different solvents reveal key factors for morphology control. Nat. Energy 10, 124–134 (2025).
Article  CAS  Google Scholar 
Xie, C. et al. Over 20% efficient water-based layer-by-layer organic solar cells with high thickness tolerance enabled by surfactant promoted electrostatic interaction. Adv. Mater. 37, e08783 (2025).
Article  CAS  PubMed  Google Scholar 
Chen, H. et al. A guest-assisted molecular-organization approach for >17% efficiency organic solar cells using environmentally friendly solvents. Nat. Energy 6, 1045–1053 (2021).
Article  CAS  Google Scholar 
Rodríguez-Martínez, X., Pascual-San-José, E. & Campoy-Quiles, M. Accelerating organic solar cell material’s discovery: high-throughput screening and big data. Energy Environ. Sci. 14, 3301–3322 (2021).
Article  PubMed  PubMed Central  Google Scholar 
Du, X. Y. et al. Elucidating the full potential of OPV materials utilizing a high-throughput robot-based platform and machine learning. Joule 5, 495–506 (2021).
Article  CAS  Google Scholar 
Burlingame, Q., Ball, M. & Loo, Y. L. It’s time to focus on organic solar cell stability. Nat. Energy 5, 947–949 (2020).
Article  Google Scholar 
Peng, Z. X., Stingelin, N., Ade, H. & Michels, J. J. A materials physics perspective on structure-processing-function relations in blends of organic semiconductors. Nat. Rev. Mater. 8, 439–455 (2023).
Article  Google Scholar 
Cheng, P. & Zhan, X. Stability of organic solar cells: challenges and strategies. Chem. Soc. Rev. 45, 2544–2582 (2016).
Article  CAS  PubMed  Google Scholar 
Reese, M. O. et al. Consensus stability testing protocols for organic photovoltaic materials and devices. Sol. Energy Mater. Sol. Cells 95, 1253–1267 (2011).
Article  CAS  Google Scholar 
Ding, P., Yang, D., Yang, S. & Ge, Z. Stability of organic solar cells: toward commercial applications. Chem. Soc. Rev. 53, 2350–2387 (2024).
Article  CAS  PubMed  Google Scholar 
Ghasemi, M. et al. A molecular interaction-diffusion framework for predicting organic solar cell stability. Nat. Mater. 20, 525–532 (2021).
Article  CAS  PubMed  Google Scholar 
Lu, Q. et al. A review on encapsulation technology from organic light emitting diodes to organic and perovskite solar cells. Adv. Funct. Mater. 31, 2100151 (2021).
Article  CAS  Google Scholar 
Yang, W. et al. Simultaneous enhanced efficiency and thermal stability in organic solar cells from a polymer acceptor additive. Nat. Commun. 11, 1218 (2020).
Article  CAS  PubMed  PubMed Central  Google Scholar 
Yu, L. et al. Diffusion-limited crystallization: a rationale for the thermal stability of non-fullerene solar cells. ACS Appl. Mater. Interfaces 11, 21766–21774 (2019).
Article  CAS  PubMed  Google Scholar 
Liang, Y. C. et al. Organic solar cells using oligomer acceptors for improved stability and efficiency. Nat. Energy 7, 1180–1190 (2022).
Article  CAS  Google Scholar 
Lee, J. W. et al. Recent progress and prospects of dimer and multimer acceptors for efficient and stable polymer solar cells. Chem. Soc. Rev. 53, 4674–4706 (2024).
Article  CAS  PubMed  Google Scholar 
Xin, J. M. et al. Cold crystallization temperature correlated phase separation, performance, and stability of polymer solar cells. Matter 1, 1316–1330 (2019).
Article  Google Scholar 
Siddika, S. et al. Molecular interactions that drive morphological and mechanical stabilities in organic solar cells. Joule 7, 1593–1608 (2023).
Article  CAS  Google Scholar 
Yoon, S. et al. Influences of metal electrodes on stability of non-fullerene acceptor-based organic photovoltaics. Adv. Funct. Mater. 34, 2308618 (2023).
Article  Google Scholar 
Yang, Y. et al. Robust and hydrophobic interlayer material for efficient and highly stable organic solar cells. Joule 7, 545–557 (2023).
Article  CAS  Google Scholar 
Li, Y. et al. Non-fullerene acceptor organic photovoltaics with intrinsic operational lifetimes over 30 years. Nat. Commun. 12, 5419 (2021).
Article  CAS  PubMed  PubMed Central  Google Scholar 
Luke, J., Yang, E. J., Labanti, C., Park, S. Y. & Kim, J. S. Key molecular perspectives for high stability in organic photovoltaics. Nat. Rev. Mater. 8, 839–852 (2023).
Article  CAS  Google Scholar 
Han, J., Xu, H., Paleti, S. H. K., Sharma, A. & Baran, D. Understanding photochemical degradation mechanisms in photoactive layer materials for organic solar cells. Chem. Soc. Rev. 53, 7426–7454 (2024).
Article  CAS  PubMed  Google Scholar 
Wang, Y. W. et al. The critical role of the donor polymer in the stability of high-performance non-fullerene acceptor organic solar cells. Joule 7, 810–829 (2023).
Article  CAS  Google Scholar 
Xiao, M. et al. Enhance photo-stability of up-scalable organic solar cells: suppressing radical generation in polymer donors. Adv. Mater. 37, 2412746 (2025).
Article  CAS  Google Scholar 
Tournebize, A. et al. Is there a photostable conjugated polymer for efficient solar cells? Polym. Degrad. Stab. 112, 175–184 (2015).
Article  CAS  Google Scholar 
Xu, H. et al. Elucidating the photodegradation pathways of polymer donors for organic solar cells with seven months of outdoor operational stability. Nat. Photon. 19, 415–425 (2025).
Article  CAS  Google Scholar 
Burlingame, Q. et al. Intrinsically stable organic solar cells under high-intensity illumination. Nature 573, 394–397 (2019).
Article  CAS  PubMed  Google Scholar 
Xu, H. et al. Dissecting the structure-stability relationship of Y-series electron acceptors for real-world solar cell applications. Joule 7, 2135–2151 (2023).
Article  CAS  Google Scholar 
Burlingame, Q. C., Loo, Y. L. & Katz, E. A. Accelerated ageing of organic and perovskite photovoltaics. Nat. Energy 8, 1300–1302 (2023).
Article  CAS  Google Scholar 
Sun, L. et al. All-solution-processed ultraflexible wearable sensor enabled with universal trilayer structure for organic optoelectronic devices. Sci. Adv. 10, eadk9460 (2024).
Article  CAS  PubMed  PubMed Central  Google Scholar 
Song, W. et al. Advances in stretchable organic photovoltaics: flexible transparent electrodes and deformable active layer design. Adv. Mater. 36, 2311170 (2024).
Article  CAS  Google Scholar 
Lee, J. W. et al. Strain-induced power output enhancement in intrinsically stretchable organic solar cells. Joule 9, 101792 (2025).
Article  CAS  Google Scholar 
Fukuda, K. et al. A bending test protocol for characterizing the mechanical performance of flexible photovoltaics. Nat. Energy 9, 1335–1343 (2024).
Article  Google Scholar 
Zhu, L. et al. Single-junction organic solar cells with over 19% efficiency enabled by a refined double-fibril network morphology. Nat. Mater. 21, 656–663 (2022).
Article  CAS  PubMed  Google Scholar 
Almora, O. et al. Device performance of emerging photovoltaic materials (version 5). Adv. Energy Mater. 15, 2404386 (2024).
Article  Google Scholar 
Wu, J. et al. A comparison of charge carrier dynamics in organic and perovskite solar cells. Adv. Mater. 34, 2101833 (2022).
Article  CAS  PubMed  Google Scholar 
Chen, X. K. et al. A unified description of non-radiative voltage losses in organic solar cells. Nat. Energy 6, 799–806 (2021).
Article  CAS  Google Scholar 
Gillett, A. J. Do spin-triplet excitons have to be a terminal loss pathway in organic solar cells? Joule 9, 102008 (2025).
Article  Google Scholar 
Xue, P., Cheng, P., Han, R. P. S. & Zhan, X. Printing fabrication of large-area non-fullerene organic solar cells. Mater. Horiz. 9, 194–219 (2022).
Article  CAS  PubMed  Google Scholar 
Rodríguez-Martíne, X. et al. What makes thickness-tolerant organic solar cells? Adv. Energy Mater. 16, 2405735 (2025).
Article  Google Scholar 
Chang, Y. M., Hsiao, Y. T. & Tsai, K. W. Unveiling the shadows: overcoming bottlenecks in scaling organic photovoltaic technology from laboratory to industry. Adv. Energy Mater. 14, 2400064 (2024).
Article  CAS  Google Scholar 
Zheng, X. et al. Versatile organic photovoltaics with a power density of nearly 40 W g−1. Energy Environ. Sci. 16, 2284–2294 (2023).
Article  CAS  Google Scholar 
Wang, W. et al. Indoor organic photovoltaic module with 30.6% efficiency for efficient wireless power transfer. Nano Energy 128, 109893 (2024).
Article  CAS  Google Scholar 
Cui, Y. et al. Wide-gap non-fullerene acceptor enabling high-performance organic photovoltaic cells for indoor applications. Nat. Energy 4, 768–775 (2019).
Article  CAS  Google Scholar 
Download references
D.B. and A.S. thank the King Abdullah University of Science and Technology (KAUST) Office of Sponsored Research (OSR) for support under award no. OSR-2019-CARF/CCF-3079. Part of the research reported in this publication was supported by funding from King Abdullah University of Science and Technology (KAUST) – Center of Excellence for Renewable Energy and Storage Technologies, under award number 5937. J.H. thanks the Alexander von Humboldt Foundation and is grateful for support during his stay with T. B. Marder’s group at Julius-Maximilians-Universität Würzburg.
Jianhua Han
Present address: State Key Laboratory of Fine Chemicals, Frontier Science Center for Smart Materials, School of Chemical Engineering, Dalian University of Technology, Dalian, China
Material Science and Engineering Program (MSE), Physical Sciences and Engineering Division (PSE), King Abdullah University of Science and Technology (KAUST), Thuwal, Kingdom of Saudi Arabia
Jianhua Han, Han Xu, Daniel Corzo, Anirudh Sharma & Derya Baran
Institut für Anorganische Chemie and Institute for Sustainable Chemistry & Catalysis with Boron (ICB), Julius-Maximilians-Universität Würzburg, Würzburg, Germany
Jianhua Han
Sensor Systems, Silicon Austria Labs GmbH, Villach, Austria
Daniel Corzo
PubMed Google Scholar
PubMed Google Scholar
PubMed Google Scholar
PubMed Google Scholar
PubMed Google Scholar
D.B. and J.H. contributed to the conception, writing and editing of every section of the Review. J.H. drafted the initial paper, and H.X., D.C. and A.S. thoroughly edited and refined each section, providing valuable insights. All authors contributed to discussing, editing and reviewing the paper before submission.
Correspondence to Derya Baran.
The authors declare no competing interests.
Nature Materials thanks Bryon Larson, Chang-Zhi Li and the other, anonymous, reviewer(s) for their contribution to the peer review of this work.
Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Figs 1–25, Notes 1 and 2, and Tables 1–10.
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
Reprints and permissions
Han, J., Xu, H., Corzo, D. et al. Pathways to commercially viable organic photovoltaic materials. Nat. Mater. (2026). https://doi.org/10.1038/s41563-026-02501-0
Download citation
Received:
Accepted:
Published:
Version of record:
DOI: https://doi.org/10.1038/s41563-026-02501-0
Anyone you share the following link with will be able to read this content:
Sorry, a shareable link is not currently available for this article.

Provided by the Springer Nature SharedIt content-sharing initiative
Advertisement
Nature Materials (Nat. Mater.)
ISSN 1476-4660 (online)
ISSN 1476-1122 (print)
© 2026 Springer Nature Limited
Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

source

This entry was posted in Renewables. Bookmark the permalink.

Leave a Reply