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Nature Photonics (2026)
Thermal instability under temperature fluctuations remains a critical challenge for the practical deployment of perovskite solar cells. Here we report a wide-temperature-range fluid-phase grain boundary (WTR-FGB) strategy enabled by incorporating a molecular complex that remains fluid between −40 °C and 85 °C. When introduced into polycrystalline perovskite films, this molecular complex is found to preferentially localize at grain boundaries, forming a dynamically adaptive and mechanically compliant intergranular network. This WTR-FGB configuration appears to accommodate thermally induced lattice mismatch, mitigate strain accumulation and suppress defect evolution during thermal cycling. Correspondingly, perovskite films exhibit enhanced structural integrity, improved photoluminescence stability and reduced morphological degradation under repeated temperature variations. These material-level changes are associated with improved device performance, enabling n–i–p perovskite solar cells with a certified power conversion efficiency of 26.52%. Thermal cycling durability is also improved, with p–i–n devices retaining over 92% of initial power conversion efficiencies after 200 cycles in accordance with the International Electrotechnical Commission 61215 standard. This work suggests that mechanically adaptive WTR-FGB engineering may offer an effective pathway towards improving the efficiency and thermal robustness of perovskite photovoltaic devices under operational temperature fluctuations.
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The main data supporting the findings of this study are available within the article and its Supplementary Information. Additional data are available from the corresponding authors upon reasonable request.
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We thank J. Yue and Y. Wei from Bruker (Beijing) Scientific Technology for their assistance with temperature-dependent AFM and nanoscale dynamic mechanical analysis measurements, respectively. We acknowledge the Shenzhen HUASUAN Technology for assistance with theoretical calculations and simulations. We also acknowledge L. Ge from NT-MDT SI Beijing office for his help on the AFM-LFM measurement, and H. Liu from Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences for his help on calculations. We gratefully acknowledge the BL 03HB beamline of the Shanghai Synchrotron Radiation Facility (SSRF) and the User Experiment Assist System of SSRF for experimental help of GIWAXS. We also thank the 1W1A-Diffuse X-ray Scattering Beamline of Beijing Synchrotron Radiation Facility (https://cstr.cn/31109.02.BSRF.1W1A) for providing technical support and assistance in GIWAXS data collection.
This work was financially supported by National Natural Science Foundation of China under grant nos. 52203208 (L.Z.), 52325310 (R.Z.), U24A6003 (R.Z.), 52272179 (L.Z.), 52373260 (W. Hu) and 52303217 (J.W.), the Young Elite Scientists Sponsorship Program by CAST under grant no. YESS20240571 (L.Z.), Yunnan Provincial Science and Technology Project at Southwest United Graduate School under grant no. 202302AO370013 (R.Z.) and the R&D Fruit Fund under grant no. 20210001 (R.Z.). This work was also sponsored by Beijing Nova Program under contract no. 20230484480 (L.Z.) and Hundred Talents Program (B) of the Chinese Academy of Sciences under grant no. E2XBRD1 (P.T.).
These authors contributed equally: Lichen Zhao, Hongyu Xu, Yanran Wang, Qiuyang Li, Wei Hu.
Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing, China
Lichen Zhao, Hongyu Xu, Wei Hu, Bo Yang, Yuanwei Chen & Huai Yang
State Key Laboratory for Artificial Microstructure and Mesoscopic Physics, School of Physics, Frontiers Science Center for Nano-optoelectronics and Collaborative Innovation Center of Quantum Matter, Peking University, Beijing, China
Lichen Zhao, Hongyu Xu, Yanran Wang, Qiuyang Li, Hao-Hsin Chen, Weizheng Huang, Qihuang Gong & Rui Zhu
Chinese Academy of Sciences, Shanghai Institute of Optics and Fine Mechanics, Shanghai, China
Yifan Zheng
School of Materials Science and Engineering, Peking University, Beijing, China
Zichen Wang & Huai Yang
Key Laboratory for Advanced Optoelectronic Integrated Chips of Jiangsu Province, Peking University Yangtze Delta Institute of Optoelectronics, Nantong, China
Jiang Wu, Chunsheng Li, Qihuang Gong & Rui Zhu
Research Center for Applied Sciences, Academia Sinica, Taipei, Taiwan
Wen-Yi Yu & Jing-Jong Shyue
Experimental Center for Advanced Materials, School of Materials Science and Engineering, Beijing Institute of Technology, Beijing, China
Tinglu Song
2020 X-Lab, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai, China
Yiping Zhao & Pengyi Tang
Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Beijing, China
Yu Chen
Shanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai, China
Xingyu Gao
Collaborative Innovation Center of Extreme Optics, Shanxi University, Taiyuan, China
Qihuang Gong & Rui Zhu
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L.Z., W. Hu, Yuanwei Chen and R.Z. conceived of the idea of the work. R.Z., L.Z. and Yuanwei Chen directed and supervised the project. L.Z., H.X., W. Hu, Y.W. and H.Y. designed the experiments. W. Hu, Yuanwei Chen and H.Y. synthesized, provided and characterized the screened molecules (POM, DSC and NMR measurements). H.X. and L.Z. conducted the viscosity measurement. H.X. and Y.W. fabricated all perovskite films and devices for characterizations, fabricated the n–i–p PSCs with assistance from B.Y. and performed the SEM measurements. Y.W. conducted the EDS analysis. Q.L. and Y.W. fabricated and tested the p–i–n PSCs. Q.L., H.X. and L.Z. contributed to the certification of PSCs. Z.W. carried out part of the theoretical calculations. Y.W., H.X., W. Huang, B.Y. and H.-H.C. performed the in situ GIWAXS measurements with support from Yu Chen and X.G., and H.X. and Y.W. analysed the results. J.W. and C.L. fabricated and tested the p–i–n minimodules. H.X., L.Z. and T.S. contributed to the ToF-SIMS measurement, and Q.L. analysed the corresponding data. W.-Y.Y. and J.-J.S. conducted the in situ XPS measurements and analysed the results together with Y.W. and L.Z. Y. Zhao and P.T. performed the HRTEM, STEM and EELS measurements and analysed the data. H.X. carried out the PL, PLQY, FTIR and thermal cycling measurements (−40 °C to 85 °C) of PSCs. Y. Zheng performed the extreme thermal stress tests (−120 °C to 120 °C) of PSCs. Y.W. performed the SCLC, in situ temperature-dependent AFM and nanoscale dynamic mechanical analysis measurement and analysed data with L.Z. B.Y. and Y.W. conducted the contact angle measurements. L.Z. and Y.W. analysed the calculation and simulation results. Q.G. gave suggestions on the optoelectronic characterizations. L.Z. and H.X. wrote the first draft of the paper. L.Z., W. Hu, Yuanwei Chen, H.Y., Q.G. and R.Z. revised the paper. All authors reviewed and commented on the paper.
Correspondence to Lichen Zhao, Wei Hu, Yuanwei Chen, Huai Yang or Rui Zhu.
The authors declare no competing interests.
Nature Photonics thanks the anonymous reviewers for their contribution to the peer review of this work.
Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Notes 1–6, Figs. 1–48 and Tables 1–6.
Time-dependent evolution of F5, F7, F9 and their mixtures (F57, F59, F79 and F579) in vessels during inversion, illustrating their flow behaviour at room temperature.
Time-resolved AIMD simulation of a bare perovskite surface without F579 adsorption at −40 °C over a 10-ps trajectory.
Time-resolved AIMD simulation of a perovskite surface with F579 adsorption at −40 °C over a 10-ps trajectory.
Time-resolved AIMD simulation of a bare perovskite surface without F579 adsorption at 85 °C over a 10-ps trajectory.
Time-resolved AIMD simulation of a perovskite surface with F579 adsorption at 85 °C over a 10-ps trajectory.
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Zhao, L., Xu, H., Wang, Y. et al. Wide-temperature-range fluid-phase grain boundaries for temperature-robust perovskite solar cells. Nat. Photon. (2026). https://doi.org/10.1038/s41566-026-01943-x
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