Synergistic Additives Enable Efficient Slot-Die-Coated Perovskite Solar Cells and Modules
A research team led by Prof. YANG Dong from the Dalian Institute of Chemical Physics of the Chinese Academy of Sciences, working in collaboration with researchers from Dalian Jiaotong University, has developed a synergistic additive strategy to facilitate the large-area slot-die coating of methylammonium-free perovskite films. Reported in the journal Advanced Materials, the fabrication approach directly tackles the chemical and physical crystallization barriers that have long hindered the scalable deposition of high-performance perovskite solar cells under ambient-air processing conditions. The collaborative research demonstrates an effective chemical pathway to stabilize scalable processing, marking a key advance toward viable industrial manufacturing.
Slot-die coating represents a highly promising manufacturing route toward the industrial-scale commercial production of perovskite photovoltaics, primarily because the technique offers exceptionally high material utilization and seamless compatibility with continuous roll-to-roll manufacturing workflows.
Despite these fundamental operational advantages, the practical application of the methylammonium-free FAxCs1-xPbI3 chemical system has remained difficult during ambient-air coating procedures. The material system exhibits an intrinsically slower crystallization rate alongside a pronounced tendency toward phase segregation when exposed to ambient atmospheric conditions. These combined physical behaviors severely complicate wet-film control, impede uniform crystal formation during open-air deposition, and ultimately compromise the structural phase stability of the resulting perovskite thin films.
To overcome these crystallization hurdles, the researchers devised a targeted synergistic additive system combining formamidinium thiocyanate, abbreviated as FASCN, with rubidium thiocyanate, known as RbSCN. Rather than acting independently, the two chemical additives provide complementary functions across distinct stages of the crystallization sequence, simultaneously guiding the initial nucleation events and stabilizing the desirable crystal structure of the absorbing layer throughout the full coating procedure.
Within this dual-additive mechanism, formamidinium thiocyanate acts primarily to promote uniform crystal nucleation during vacuum-flash treatment and to support subsequent crystal grain growth across the coated area. Concurrently, rubidium thiocyanate functions to preserve and stabilize the photoactive perovskite crystal phase. Specifically, rubidium cations integrate directly into the A site of the perovskite crystal lattice, which relaxes internal lattice strain, lowers the necessary activation energy barrier for forming the photoactive alpha-FAPbI3 phase, and effectively suppresses the emergence of the undesired, non-photoactive delta-FAPbI3 phase.
By coordinating these complementary crystallization dynamics, the research team successfully expanded the permissible processing window for achieving uniform perovskite crystallization to more than 100 seconds. This prolonged operational window allows sufficient time for controlled film solidification, producing thin films that feature a remarkably dense microstructure, noticeably large crystal grains, a uniform vertical compositional gradient throughout the layer thickness, and significantly reduced residual internal stress across the finished film.
When fabricated into small-area perovskite solar cells, the slot-die-coated devices delivered a high power conversion efficiency of 26.16 percent. Furthermore, when the team scaled the fabrication technique to a large-area module featuring an active surface area of 54.80 square centimeters, the device achieved a power conversion efficiency of 22.70 percent, outperforming the 15.8 percent efficiency recorded for an additive-free control module.
In addition to delivering elevated power conversion efficiencies, the synergistic additive formulation substantially enhanced the long-term operational durability of the photovoltaic devices under continuous operational stress. During maximum-power-point tracking evaluation conducted continuously under standard AM 1.5G solar illumination at an elevated operating temperature of 65 degrees Celsius, unencapsulated solar cells retained 97.76 percent of their initial power conversion efficiency after 1,300 hours of continuous operation, in stark contrast to control devices which retained only 65.86 percent of their original efficiency under identical testing parameters.
Subject of Research: Scalable slot-die coating of methylammonium-free perovskite solar cells using synergistic additives
Article Title: Researchers develop synergistic additives for scalable slot-die-coated perovskite photovoltaics
Article References: Researchers develop synergistic additives for scalable slot-die-coated perovskite photovoltaics. Original publication (Bibliographic details unavailable.)
Image Credits: AI Generated
DOI: Not provided
Keywords: Perovskite photovoltaics, Slot-die coating, Methylammonium-free perovskites, FAxCs1-xPbI3, Formamidinium thiocyanate, Rubidium thiocyanate, FASCN, RbSCN, Perovskite crystallization, Alpha-FAPbI3 phase, Delta-FAPbI3 suppression, Vacuum-flash treatment, Large-area solar modules, Power conversion efficiency, Maximum-power-point tracking, Operational stability, Dalian Institute of Chemical Physics
News Source: Bethany Barker. (November 11, 2026). Synergistic Additives Enable Efficient Slot-Die-Coated Perovskite Solar Cells and Modules. Scienmag.
We bring you the latest biotechnology news from best research centers and universities around the world. Check our website.
Enter your email address to subscribe to this blog and receive notifications of new posts by email.
Email Address
Subscribe
Bioengineer.org © Copyright 2023 All Rights Reserved.
Login to your account below


Remember Me

Please enter your username or email address to reset your password.


Bioengineer.org © Copyright 2023 All Rights Reserved.

source