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Nature Synthesis (2026)
Self-assembled monolayers serve as hole-selective contacts in perovskite solar cells, but their scalable fabrication remains challenging. Here we report a rapid (≤5 min) soak-coating strategy for self-assembled monolayer fabrication, enabled by molecular design and solvent engineering. The unsymmetric self-assembled monolayer material (4-(10-methoxy-7H-benzo[c]carbazol-7-yl)phenyl)phosphonic acid was rationally designed with dual-functional molecular segments to inhibit molecular aggregation in solution and enhance interfacial charge transport. Concurrently, an ethanol-based solvent system containing 1.5 vol% water was engineered to improve material dispersity and strengthen surface anchoring on transparent conducting oxide substrates. The soak-coated self-assembled monolayers exhibit dense and uniform coverage, yielding perovskite solar cells with a certified power conversion efficiency of 27.23%. This methodology demonstrates good scalability, successfully extending to large-area devices, mini-modules and flexible architectures, all of which maintain stable operation. Notably, both the soak-coating solutions and modified transparent conducting oxide substrates can be reused, substantially improving resource efficiency. This work provides a scalable and cost-efficient route for fabricating stable perovskite solar cells.
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All data generated or analysed during this study are available within the paper and its Supplementary Information. Source data are provided with this paper.
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We acknowledge the SUSTech Core Research Facilities for technical support and X. Chen (SUSTech) for assistance with the grazing-incidence reflection Fourier transform infrared measurements.
Z.-X.X. discloses support for the research of this work from the National Natural Science Foundation of China (grant number 22479071) and the Shenzhen Science and Technology Innovation Commission (grant number 20231115141039001). A.K.-Y.J. discloses support for the research of this work from the Lee Shau-Kee Chair Professor (Materials Science), the APRC Grants of the City University of Hong Kong (grant numbers 9380086, 9610419, 9610440, 9610492, 9610508), the MHKJFS grant (number MHP/054/23) and the TCFS grant (number GHP/121/22SZ) from the Innovation and Technology Commission of Hong Kong, the GRF grants (numbers 11307621, 11316422, 11308625) and the CRS grants (numbers CRS_CityU104/23, CRS_HKUST203/23] from the Research Grants Council of Hong Kong, and City University of Hong Kong (grant number 9610739) through the project ‘Fostering Innovation for Resilience and Sustainable Transformation’, officially endorsed by the United Nations Educational, Scientific and Cultural Organization under the International Decade of Sciences for Sustainable Development (2024–2033). F.G. discloses support for the research of this work from the Swedish Energy Agency (grant number P2023-01307). The other authors declare no relevant funding.
These authors contributed equally: Geping Qu, Siyuan Cai, Yuli Tao, Letian Zhang, Ying Qiao.
Department of Chemistry, Southern University of Science and Technology, Shenzhen, China
Geping Qu, Siyuan Cai, Letian Zhang, Ying Qiao, Yuanjia Ding, Zicheng Zhang & Zong-Xiang Xu
Department of Materials Science and Engineering, City University of Hong Kong, Hong Kong, China
Geping Qu & Alex K.-Y. Jen
Institute of Solid-State Physics, Hefei Institutes of Physical Science, Chinese Academy of Science, Hefei, China
Yuli Tao & Xu Pan
Department of Applied Physics, The Hong Kong Polytechnic University, Hung Hom, Hong Kong, China
Ying Qiao
Henan Key Laboratory of Quantum Materials and Quantum Energy, School of Future Technology, Henan University, Zhengzhou, China
Jie Yang & Shi Chen
Department of Mechanical and Energy Engineering, SUSTech Energy Institute for Carbon Neutrality, Southern University of Science and Technology, Shenzhen, China
Jun Fang & Longbin Qiu
Department of Chemistry, City University of Hong Kong, Hong Kong, China
Xiaofeng Huang & Alex K.-Y. Jen
Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping, Sweden
Niansheng Xu & Feng Gao
Department of Materials Science and Engineering, University of Washington, Seattle, WA, USA
Alex K.-Y. Jen
State Key Laboratory of Marine Pollution, City University of Hong Kong, Hong Kong, China
Alex K.-Y. Jen
Hong Kong Institute for Clean Energy (HKICE), City University of Hong Kong, Hong Kong, China
Alex K.-Y. Jen
Shenzhen MOLEC New Energy Technology Co., Ltd., Shenzhen, China
Zong-Xiang Xu
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G.Q., L.Z., S. Cai, F.G. and Z.-X.X. conceived of and designed the research. G.Q. carried out the fabrication and major characterization of PSCs. Y.T. and X.P. carried out the fabrication of PSMs. Y.Q. conducted theoretical simulations. L.Z., S. Cai and Z.Z. synthesized and characterized the SAM molecules. J.Y., Y.D. and X.H. performed GIWAX, SEM, electrochemical impedance spectroscopy and mass spectrometry measurements. J.F. and L.Q. conducted the photoluminescence mapping. S. Chen, N.X. and A.K.-Y.J. contributed to the analysis and provided advice. G.Q., Y.Q. and Z.-X.X. wrote the initial draft, and all authors contributed to the final paper.
Correspondence to Ying Qiao, Xu Pan, Feng Gao, Alex K.-Y. Jen or Zong-Xiang Xu.
The authors declare no competing interests.
Nature Synthesis thanks Ershad Parvazian and the other, anonymous, reviewer(s) for their contribution to the peer review of this work. Peer reviewer reports are available. Primary Handling Editor: Alexandra Groves, in collaboration with the Nature Synthesis team.
Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Notes 1–15, Figs. 1–75, Tables 1–22 and Refs. 1–18.
SAM solubility comparison.
Source data for Fig. 1c–e,g.
Source data for Fig. 2a,d,e,j,i.
Source data for Fig. 3c–f,h.
Source data for Fig. 1a,c–h.
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Qu, G., Cai, S., Tao, Y. et al. A self-assembled monolayer via rapid and scalable soak coating for perovskite solar cells. Nat. Synth (2026). https://doi.org/10.1038/s44160-026-01089-2
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