Trina Solar Proposes Reversible and Irreversible Classification for UV-Induced Degradation in TOPCon Cells – IndexBox

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Researchers at the Chinese solar manufacturer Trina Solar have put forward a new way of classifying ultraviolet-induced degradation in TOPCon solar cells, separating the phenomenon into a reversible form and an irreversible form, according to pv magazine. The proposal, reported by the solar trade publication, is intended to sharpen reliability assessments, bring greater consistency to testing procedures, and improve forecasts of how modules will perform over the long term under real operating conditions.
The team behind the work said the two categories it proposes line up with the recovery steps envisioned in a forthcoming technical specification from the International Electrotechnical Commission, known as IEC TS 63624-1, which is being drawn up to standardize laboratory protocols for evaluating UV-induced degradation in crystalline silicon solar modules.
According to the corresponding author, Zhiwei Li, aligning the proposed definitions with the pending IEC standard is meant to create a shared vocabulary spanning standardization, reliability testing, warranty assessments and project financing. In comments reported by pv magazine, Li said this would allow more consistent evaluations of long-term performance risk and help separate temporary, recoverable power losses from permanent degradation that affects actual energy yield.
The researchers describe pronounced metastability as a defining trait of UV-induced degradation in TOPCon cells. After UV exposure, cells can lose further performance while in dark storage, driven mainly by a drop in open-circuit voltage and marked by double-exponential degradation kinetics. Much of that added degradation is reversible, the team said, and can be recovered through light soaking or thermal annealing, processes that encourage hydrogen redistribution and changes in charge trapping at passivation interfaces.
Field tests cited by the researchers confirmed that this metastable loss does not affect actual outdoor energy yield, because daily sunlight enables dynamic recovery. The severity of the degradation depends strongly on the thickness and deposition method of the aluminum oxide layer, on hydrogen content and bonding configuration, and on the choice of capping layer, with thicker aluminum oxide and silicon oxynitride capping providing better resilience, according to the team.
The researchers also pointed to pronounced variability between manufacturers, reflecting differences in wafer quality, passivation deposition processes and emitter doping profiles.
Unlike conventional UV preconditioning tests, which generally use relatively low UV doses and may fail to capture mechanisms specific to TOPCon cells, the proposed approach applies substantially higher UV exposure followed by a standardized light-soaking recovery step. According to the scientists, this extra step lets researchers tell temporary, reversible losses apart from persistent degradation that remains after recovery, giving a more realistic picture of long-term module reliability and possible effects on outdoor energy yield.
The team said better front-side passivation will be central to limiting the degradation. One of the most effective strategies involves optimizing the thickness and deposition method of the aluminum oxide layer. Excessively thick layers of that material, however, can cause blistering, add interface defects and raise tunneling resistance. Alternative capping materials, especially silicon oxynitride, also show promise by stabilizing hydrogen, reducing interfacial charge interference and improving chemical passivation.
The researchers noted that atomic layer deposition, particularly the plasma-enhanced variant, generally delivers better UV resistance than conventional plasma-enhanced chemical vapor deposition, though performance depends on the specific process. They also recommended adjusting the refractive index of silicon nitride to boost UV absorption and protect underlying interfaces, while warning that excessive absorption may reduce optical efficiency.
Hydrogen management was identified as another critical mitigation strategy, since hydrogen can both passivate defects and contribute to degradation when released or redistributed under UV exposure. Optimizing deposition temperatures, gas compositions, firing profiles and annealing conditions can help preserve beneficial hydrogen bonding while limiting the formation of recombination-active defects, according to the team.
Li said the combined effects of environmental stresses, particularly heat and ultraviolet radiation, require further investigation and more representative reliability tests. He also noted that differences between UV aging light sources, including fluorescent and metal halide lamps, need standardized equivalence criteria, and that the influence of ultraviolet-B radiation on degradation rates relative to ultraviolet-A remains insufficiently quantified.
Li added that researchers have observed differing degradation patterns among electrical parameters, particularly between short-circuit current and passivation-related characteristics, but that the underlying mechanisms remain unclear. He said targeted mitigation strategies for the irreversible form of degradation are still underdeveloped, highlighting the need for systematic approaches to prevent persistent performance losses and improve long-term module reliability.
The proposed classification is presented in a paper titled Ultraviolet-induced degradation in TOPCon solar cells: Reversible (r-UVID) and irreversible (ir-UVID) degradation, mechanisms and mitigation strategies, recently published in Solar Energy Materials and Solar Cells.
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Energy-Storage Market Structure and Company Archetypes
Largest solar cell manufacturer by capacity
Vertically integrated from wafers to modules
Strong presence in utility-scale and distributed markets
Pioneer in high-efficiency modules
Listed on NASDAQ, operations based in China
Vertically integrated with global manufacturing
Known for high-power modules and overseas factories
Focus on distributed generation and utility projects
Brand Astronergy known for high-efficiency panels
Maxeon is spin-off, China HQ for manufacturing
Restructured, still active in manufacturing
Part of Hanwha Group, China-based factories
Part of Zhongli Group, exports globally
Strong in European and Asian markets
Restructured, still produces modules
Restructured, continues module production
Also produces cells for internal use
Subsidiary of TBEA, integrated supply chain
Restructured under Wuxi Industrial Development
Focus on high-efficiency PERC cells
Known for TOPCon and bifacial modules
Focus on high-efficiency back-contact cells
Active in distributed generation
Focus on off-grid and portable solar
Successor to original Suntech brand
Focus on high-efficiency cell production
Part of SAS group, Taiwan-linked but China HQ
Focus on next-gen high-efficiency cells
Listed on NYSE, China-based manufacturing
Focus on customized solar products
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